学術論文/総説・著書

“Arylation of Hydrocarbyl Ligands Formed from n-Alkanes through C-H Bond Activation of Benzene Using a Triruthenium Cluster”

Makoto Moriya, Atsushi Tahara, Toshiro Takao, Hiroharu Suzuki

Eur. J. Inorg. Chem. 2009, 23, 3393-3397.

DOI: 10.1002/ejic.200900519

Arylation of Hydrocarbyl Ligands Formed from n-Alkanes through C-H Bond Activation of Benzene Using a Triruthenium Cluster

“Metathesis Reaction of Hydrocarbyl Ligands across the Triruthenium Plane”

Atsushi Tahara, Mana Kajigaya, Makoto Moriya, Toshiro Takao, Hiroharu Suzuki

Angew. Chem. Int. Ed. 2010, 49(34), 5898-5901.

DOI: 10.1002/anie.201002235

● Featured as Highlight (Angew. Chem. Int. Ed. 2012, 51, 5794-5796.)

Metathesis Reaction of Hydrocarbyl Ligands across the Triruthenium Plane

“Development of Metathesis Reaction of Hydrocarbyl Ligands using a Trimetallic Complex”

Atsushi Tahara

Bull. Jpn. Soc. Coord. Chem. 2011, 57, 125-127.

DOI: 10.4019/bjscc.57.125


“Synthesis and dynamic properties of a triruthenium complex containing μ3η2(∥)-ethyne and μ3-methylidyne ligands: equilibrium of an ethyne-hydrido complex with a nonclassical μ3-vinyl complex”

Atsushi Tahara, Mana Kajigaya, Toshiro Takao, Hiroharu Suzuki

Organometallics 2013, 32(1), 260-271.

DOI: 10.1021/om301064y

Synthesis and dynamic properties of a triruthenium complex containing m3-h2(||)-ethyne and m3-methylidyne ligands: equilibrium of an ethyne-hydrido complex with a nonclassical m3-vinyl complex

“Me2S-induced highly selective reduction of aldehydes in the presence of ketones involving aldehyde-selective rate enhancement: a triruthenium cluster-catalyzed hydrosilylations”

Shohei Yumino, Toru Hashimoto, Atsushi Tahara, Hideo Nagashima

Chem. Lett. 2014, 43(12), 1829-1831.

DOI: 10.1246/cl.140731

Me2S-induced highly selective reduction of aldehydes in the presence of ketones involving aldehyde-selective rate enhancement: a triruthenium cluster-catalyzed hydrosilylations

“Regio- and stereoselective synthesis of multisubstituted enamides by treatment of ynamides with boronic acids”

Atsushi Tahara

J. Synth. Org Chem. Jpn. 2015, 73(7), 749-750.

DOI: 10.5059/yukigoseikyokaishi.73.749


“Catalyst Design of Vaska-Type Iridium Complexes for Highly Efficient Synthesis of π-Conjugated Enamines”

Atsushi Tahara, Yasumitsu Miyamoto, Ryuta Aoto, Keisuke Shigeta, Yuta Une, Yusuke Sunada, Yukihiro Motoyama, Hideo Nagashima

Organometallics 2015, 34(20), 4895-4907.

DOI: 10.1021/acs.organomet.5b00636

Catalyst Design of Vaska-Type Iridium Complexes for Highly Efficient Synthesis of p-Conjugated Enamines

“Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes”

Daisuke Noda, Atsushi Tahara, Yusuke Sunada, Hideo Nagashima

J. Am. Chem. Soc. 2016, 138(8), 2480-2483.

DOI: 10.1021/jacs.5b11311

● Selected as Front Cover.

● Featured as Spotlight (J. Am. Chem. Soc. 2016, 138(8), 2455-2456.)

● Selected as “Select Research Articles from 2016” in JACS

● Featured in Chem-Station (2016/3/9)

Selected as “Select Research Articles from 2016” in JACS
Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

“Theoretical Study of the Catalytic Hydrogenation of Alkenes by a Disilaferracyclic Complex: Can the Fe-Si σ-Bond-Assisted Activation of H-H Bonds Allow Development of a Catalysis of Iron?”

Atsushi Tahara, Hiromasa Tanaka, Yusuke Sunada, Yoshihito Shiota, Kazunari Yoshizawa, Hideo Nagashima

J. Org. Chem. 2016, 81(22), 10900-10911.

DOI: 10.1021/acs.joc.6b01961

Theoretical Study of the Catalytic Hydrogenation of Alkenes by a Disilaferracyclic Complex: Can the Fe-Si s-Bond-Assisted Activation of H-H Bonds Allow Development of a Catalysis of Iron?

 “σ-CAM mechanisms for the hydrogenation of alkenes by cis– and trans-disilametallacyclic carbonyl complexes (M = Fe, Ru, Os): experimental and theoretical studies”

Konoka Hoshi, Atsushi Tahara, Yusuke Sunada, Hironori Tsutsumi, Ryoko Inoue, Hiromasa Tanaka, Yoshihito Shiota, Kazunari Yoshizawa, Hideo Nagashima

Bull. Chem. Soc. Jpn. 2017, 90(5), 613-626.

DOI: 10.1246/bcsj.20170004

Selected as BCSJ award (Vol 90, No. 5, 2017)

● Selected as Front Cover

Selected as BCSJ award (Vol 90, No. 5, 2017) Selected as Front Cover
s-CAM mechanisms for the hydrogenation of alkenes by cis- and trans-disilametallacyclic carbonyl complexes (M = Fe, Ru, Os): experimental and theoretical studies

“Disilaruthena- and Ferracyclic Complexes Containing Isocyanide Ligands as Effective Catalysts for Hydrogenation of Unfunctionalized Sterically Hindered Alkenes”

Yusuke Sunada, Hajime Ogushi, Taiji Yamamoto, Shoko Uto, Mina Sawano, Atsushi Tahara, Hiromasa Tanaka, Yoshihito Shiota, Kazunari Yoshizawa, Hideo Nagashima

J. Am. Chem. Soc. 2018, 140(11), 4119-4134.

DOI: 10.1021/jacs.8b00812

● Selected as a Finalist of Supplementary Front Cover

Selected as a Finalist of Supplementary Front Cover
Disilaruthena- and Ferracyclic Complexes Containing Isocyanide Ligands as Effective Catalysts for Hydrogenation of Unfunctionalized Sterically Hindered Alkenes

“Novel application of nanoscale zero valent iron and bimetallic nano-Fe/Cu particles for the treatment of cesium contaminated water”

Tamer Shubair, Osama Eljamal, Ahmed M. E. Khali, Atsushi Tahara, Nobuhiro Matsunaga

J. Environment. Chem. Eng. 2018, 6(4), 4253-4264.

DOI: 10.1016/j.jece.2018.06.015

Novel application of nanoscale zero valent iron and bimetallic nano-Fe/Cu particles for the treatment of cesium contaminated water

“Syntheses of Substituted 1,4-Disila-2,5-cyclohexadienes from Cyclic Hexasilane Si6Me12 and Alkynes via Successive Si-Si Bond Activation by Pd/Isocyanide Catalysts”

Atsushi Tahara, Shunsuke Nagino, Yusuke Sunada, Ryohei Haige, Hideo Nagashima

Organometallics 2018, 37(15), 2531-2453.

DOI: 10.1021/acs.organomet.8b00302

Syntheses of Substituted 1,4-Disila-2,5-cyclohexadienes from Cyclic Hexasilane Si6Me12 and Alkynes via Successive Si-Si Bond Activation by Pd/Isocyanide Catalysts

“Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds”

Atsushi Tahara, Yusuke Sunada, Takashi Takeshita, Ryoko Inoue, Hideo Nagashima

Chem. Commun. 2018, 54(79), 11192-11195.

DOI: 10.1039/C8CC04780D

Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

“Transformation of a μ3-Benzyne Ligand into Phenol on a Cationic Triruthenium Cluster Supported by a μ3-Sulfido Ligand”

Hiroki Chikamori, Atsushi Tahara, Toshiro Takao

Organometallics 2019, 38(4), 527-535.

DOI: 10.1021/acs.organomet.8b00832

Transformation of a μ3-Benzyne Ligand into Phenol on a Cationic Triruthenium Cluster Supported by a μ3-Sulfido Ligand

“Iron based nanoparticles-zeolite composites for the removal of cesium from aqueous solutions”

Osama Eljamal, Tamer Shubair, Atsushi Tahara, Yuji Sugihara, Nobuhiro Matsunaga

J. Mol. Liq. 2019, 277, 613-623.

DOI: 10.1016/j.molliq.2018.12.115

Iron based nanoparticles-zeolite composites for the removal of cesium from aqueous solutions

“Iridium-PPh3 Catalysts for Conversion of Amides to Enamines”

Yuta Une, Atsushi Tahara, Yasumitsu Miyamoto, Yusuke Sunada, Hideo Nagashima

Organometallics 2019, 38(4), 852-862.

DOI: 10.1021/acs.organomet.8b00835

● Selected as Supplementary Front Cover

● Selected as Supplementary Front Cover
Iridium-PPh3 Catalysts for Conversion of Amides to Enamines

“MAO-free and extremely active catalytic system for ethylene tetramerization”

Tae Hee Kim, Hyun Mo Lee, Hee Soo Park, Sung Dong Kim, Su Jin Kwon, Atsushi Tahara, Hideo Nagashima, Bun Yeoul Lee

App. Organomet. Chem. 2019, 33(4), e4829.

DOI: 10.1002/aoc.4829

Selected as Inside Front Cover

● Selected as Inside Front Cover
MAO-free and extremely active catalytic system for ethylene tetramerization

 “Preparation of new magnetic zeolite nanocomposites for removal of strontium from polluted waters”

Tamer Shubair, Osama Eljamal, Atsushi Tahara, Yuji Sugihara, Nobuhiro Matsunaga

J. Mol. Liq. 2019, 288, 111026.

DOI: 10.1016/j.molliq.2019.111026

Preparation of new magnetic zeolite nanocomposites for removal of strontium from polluted waters

“Donor-Acceptor π-Conjugated Enamines: Functional Group Compatible Synthesis from Amides and Their Photoabsorption and Photoluminescence Properties”

Atsushi Tahara, Ikumi Kitahara, Daichi Sakata, Yoichiro Kuninobu, Hideo Nagashima

J. Org. Chem. 2019, 84(23), 15236-15254.

DOI: 10.1021/acs.joc.9b02267

● Selected as a Finalist of Supplementary Front Cover

● Selected as a Finalist of Supplementary Front Cover
Donor-Acceptor p-Conjugated Enamines: Functional Group Compatible Synthesis from Amides and Their Photoabsorption and Photoluminescence Properties

“Recent topics of iridium-catalyzed hydrosilylation of tertiary amides to silylhemiaminals”

Atsushi Tahara, Hideo Nagashima

Tetrahedron Lett. 2020, 61(4), 151423 (8 pages).

DOI: 10.1016/j.tetlet.2019.151423

Recent topics of iridium-catalyzed hydrosilylation of tertiary amides to silylhemiaminals

“Magnetic Zeolite Synthesis for Efficient Removal of Cesium in a Lab-scale Continuous Treatment System.”

Omar Falyouna, Osama Eljamal, Ibrahim Maamoun, Atsushi Tahara, Yuji Sugihara

J. Col. Int. Eci. 2020, 571(1), 66-79.

DOI: 10.1016/j.jcis.2020.03.028

Magnetic Zeolite Synthesis for Efficient Removal of Cesium in a Lab-scale Continuous Treatment System.

“Intramolecular Nitrene Transfer via the C≡N Bond Cleavage of Acetonitrile to a μ3-Alkylidyne Ligand on a Cationic Triruthenium Plane”

Yusuke Takahashi, Atsushi Tahara, Toshiro Takao

Organometallics 2020, 39, 2888-2899.

DOI: 10.1021/acs.organomet.0c00393

Intramolecular Nitrene Transfer via the C≡N Bond Cleavage of Acetonitrile to a m3-Alkylidyne Ligand on a Cationic Triruthenium Plane

“Sustainable Iron-Making Using Oxalic Acid: The Concept, A Brief Review of Key Reactions, and An Experimental Demonstration of the Iron-Making Process”

Phatchada Santawaja, Shinji Kudo, Aska Mori, Atsushi Tahara, Shusaku Asano, Jun-ichiro Hayashi

ACS Sus. Chem. Eng. 2020, 8, 13292-13301.

DOI: 10.1021/acssuschemeng.0c0359

Sustainable Iron-Making Using Oxalic Acid: The Concept, A Brief Review of Key Reactions, and An Experimental Demonstration of the Iron-Making Process

“The Asymmetric Kharasch Addition “On Water” Catalyzed by “RhCl[(–)-DIOP]” Species”,

Atsushi Tahara, Hikaru Takao, Hiroshi Furuno, Hideo Nagashima

Evergreen 2021, 8(3), 535-543.

DOI: 10.5109/4491639


 “An effect of metal cations for the formation of oxalates from formates”,

Atsushi Tahara

Res Ind. Sci. Res. Prom. Found. 2021, 1-8.


“Chemical deposition of iron nanoparticles (Fe0) on titanium nanowires for efficient adsorption of ciprofloxacin from water”,

Omar Falyouna, Ibrahim Maamoun, Khaoula Bensaida, Atsushi Tahara, Yuji Sugihara, Osama Eljamal

Wat. Prac. Tech. 2022, 17(1), 75-83.

DOI: 10.2166/wpt.2021.091


“Encapsulation of iron nanoparticles with magnesium hydroxide shell for remarkable removal of ciprofloxacin from contaminated water”,

Omar Falyouna, Ibrahim Maamoun, Khaoula Bensaida, Atsushi Tahara, Yuji Sugihara, Osama Eljamal,

J. Col. Int. Sci. 2022, 605, 813-827.

DOI: 10.1016/j.jcis.2021.07.154

Encapsulation of iron nanoparticles with magnesium hydroxide shell for remarkable removal of ciprofloxacin from contaminated water

“Synthesis of hybrid magnesium hydroxide/magnesium oxide nanorods [Mg(OH)2/MgO] for prompt and efficient adsorption of ciprofloxacin from aqueous solutions”,

Omar Falyouna, Khaoula Bensaida, Ibrahim Maamoun, U. P. M. Ashik, Atsushi Tahara, Kazuya Tanaka, Noboru Aoyagi, Yuji Sugihara, Osama Eljamal,

J. Clean. Prod. 2022, 342(15), 130949 (15 pages).

DOI: 10.1016/j.jclepro.2022.130949

Synthesis of hybrid magnesium hydroxide/magnesium oxide nanorods [Mg(OH)2/MgO] for prompt and efficient adsorption of ciprofloxacin from aqueous solutions

“Homogeneous catalyst modifier for alkyne semi-hydrogenation: systematic screening in an automated flow reactor and computational study on mechanisms”,

Shusaku Asano, Samuel J. Adams, Yuta Tsuji, Kazunari Yoshizawa, Atsushi Tahara, Jun-ichiro Hayashi,

React. Chem. Eng. 2022, 7, 1818-1826.

DOI: 10.1039/d2re00147k

● Featured in Chem-Station (2022/6/6)

Homogeneous catalyst modifier for alkyne semi-hydrogenation: systematic screening in an automated flow reactor and computational study on mechanisms

 “Optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particles”

Tamer Shubair, Atsushi Tahara, Shahjalal Khandaker

Case Stud. Chem. Environ. Eng. 2022, 6, 100243 (10 pages).

DOI: 10.1016/j.cscee.2022.100243

Optimizing the magnetic separation of strontium ion using modified zeolite with nano iron particles

“Dissolution of Iron Oxides Highly Loaded in Oxalic Acid Aqueous Solution for a Potential Application in Iron-Making”,

Phatchada Santawaja, Shinji Kudo, Atsushi Tahara, Shusaku Asano, Jun-ichiro Hayashi,

ISIJ International 2022, 62(12), 2466-2475.

DOI: 10.2355/isijinternational.isijint-2020-726


“Synthesis of Oxalate from CO2 and Cesium Carbonate Supported Over Porous Carbon”,

Takuya Kiyozumi, Shinji Kudo, Aska Mori, Riku Mizoguchi, Atsushi Tahara, Shusaku Asano, Jun-ichiro Hayashi,

ISIJ International 2022, 61(12), 2476-2482.

DOI: 10.2355/isijinternational.isijint-2022-159


 *preprinted “Base-Catalyzed Dehydrogenative Coupling of Formate Anions to Oxalates: Effect of Alkali Metal Cations”,

Atsushi Tahara, Aska Mori, Jun-ichiro Hayashi, Shinji Kudo,

ChemRxiv 2022, DOI: 10.26434/chemrxiv-2022-6r93n.

Base-Catalyzed Dehydrogenative Coupling of Formate Anions to Oxalates: Effect of Alkali Metal Cations

* “アルケンのヒドロシリル化用鉄・コバルト触媒の開発”

永島 英夫, 真川 敦嗣, 田原 淳士, 砂田 祐輔, 作田 晃司, 野田 大輔,

ケイ素化学協会誌 トピックス―昨日今日そして明日のケイ素化学, 2016, 33, 4-13.

(*comment: This is a review about recent topics of iron- or cobalt-catalyzed hydrosilylation of alkenes with hydrosiloxane, which was published in Japanese silicone chemistry paper.)


* “ベースメタルと典型元素による分子活性化の最近の動向”

田原 淳士

Organometallic News 2017, 2, 80.

(*comment: This is a review about recent topics of bond activation using a cooperative interaction between base metal and main metal.)


* “おらが春 寅年生れおおいに語る 昭和六十一年生”,

田原淳士,

近畿化学工業界 (きんか), 2021, 74(1), 24.

(ISSN 0912-196X).

(*comment: This is a new-year message of chemists born in 1986, which was published in Japanese organometallic chemistry paper.)